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why trisodium phosphate dosing in boiler drum – CFBC Boiler Manufac…
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Jun 12, 2017 · Trisodium phosphate reacts in the boiler to produce caustic alkalinity and raise the pH. Careful monitoring and control of boiler water chemistry is required to maintain the equilibrium balance between pH and phosphate residual. Coordinated phosphate treatment is very effective for boilers operating in the 1000 to 1500 psig range.
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Feb 08, 2021 · Back in the 1930s, as power generating units increased in number and size, trisodium phosphate (Na 3 PO 4 or TSP) became a popular boiler-water conditioning chemical for drum boilers. In the utility industry, phosphate treatment programs have undergone much evolution, with a return to just TSP, albeit in low dosages, common for modern units.
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Mar 22, 2009 · The high boiler water pH also protected boiler surfaces from corrosion. Current Phosphate Treatment Concepts Once acid phosphate corrosion was identified, the use of Congruent Phosphate Treatment (CPT) in high pressure boilers was greatly reduced. Equilibrium Phosphate Treatment (EPT) replaced CPT in many cases.
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Aug 07, 2017 · A method of fluorometrically monitoring dose control and leak detection, as well as boiler water system programs that occur in industrial systems containing boilers that operate between about 1500 psig and 2600 psig, and at pH from about 7.6 to 11.5.
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In more critical, high-pressure boilers, the most common internal treatment, in addition to scale prevention, involves the use of a phosphate program. There are three such programs, called 1. simplified phosphate 2. coordinated phosphate 3. concurrent phosphate 4. congruent phosphate 5. equilibrium phosphate a. 1,3,5 b. 2,4,5 c. 1,2,3 d. 2,3,4
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In high pressure boilers, Na 2 CO 3 decomposes to give sodium hydroxide and carbon dioxide, Na 2 CO 3 + H 2 O → 2NaOH + CO 2. and this makes the boiler water basic ["caustic"]. The NaOH containing water flows into the minute hair-cracks, always present in the inner side of boiler, by capillary action.
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The impossibility of unambiguously estimating phosphate concentration by measuring boiler-water conductivity in a high-pressure drum boiler (p b = 13.8 MPa) is shown.
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Sulfite also creates additional Total Dissolved Solids (TDS) which is a problem for high pressure applications. Hydrazine removes O2 without producing acidic gases or TDS, but is considered a possible carcinogen. Hydroxides. Sodium Hydroxide – NaOH or Caustic Soda, or Soda Ash – used to maintain boiler water pH in the 10.0 – 11.5 range.
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this modified phosphate treatment can vary between 2.4 and 2.8, while also maintaining the alkalinity high enough to minimize corrosion of carbon steel. The concentration of phosphate in boilers water is dependent on drum pressure and water quality, a typical high pressure boiler fed with de-mineralized water
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Phosphate Treatment Phosphate treatment is now universally used for all groups of boiler. Phosphate treatment is used in conjunction with either Sodium hydroxide, or Sodium carbonate How it works: Phosphate (as Trisodium phosphate) reacts with the scale forming salts to produce non-adhering sludge.
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But many high pressure boilers continue to operate at about 0.2 ppm of phosphate or lower. • Most operators were not clear about the distinct differences between EPT and PT and thus exactly where to operate. Figure 1-6 shows an artificial boundary between the two treatments at about 2.4 ppm phosphate. •
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May 23, 2017 · Phosphate Dosing Point In High Pressure Boiler - posted in Industrial Professionals: Hello, Good day everyone. Im currently working in a coal fired power plant industry with boiler pressure around 206 bar (HP, IP, and LP turbines). Today, the power plant is at its commissioning stage and I only provide support to the commissioning team such as review of …
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All-volatile treatment Coordinated Phosphate. Control of pH comes from hydrolysis of trisodium phosphate in water Na3PO4 + H2O -> Na2HPO4 + NaOH. Molar ratio of sodium : phosphate is 3 : 1 in water Feedwater contamination usually dictates caustic-consuming chemicals, such as disodium and trisodium phosphate Does not ensure absence of caustic
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Sep 15, 2015 · Phosphate/Polymer Treatment Boiler Control Parameters • Phosphate residual as PO4 depending on hardness in the feedwater • usually associated with boiler pressure • and environmental legislation • M alkalinity of 700 ppm as CaCO3 (25 % of TDS) • Polymer : min 360 ppm as SP8100 • Still the most used method for treating low pressure
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May 23, 2016 · Relatively thin localized deposits in high pressure boilers may cause damage or failure, whereas much heavier deposits can be tolerated at lower pressures, notwithstanding the loss of efficiency. The use of phosphate type internal treatment chemicals for reducing the concentration of calcium hardness is common practice.
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Mar 01, 2022 · Coordinated phosphate treatment (CPT) or captive alkalinity program was first introduced by Purcell and Whirl fulfilled in high pressure boilers operating at the range of 1000–2000 PSI. This regime helps to maintain alkalinity level of boiler water high enough and eliminate excessive free sodium hydroxide from water cycle, minimizing the
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All-volatile treatment Coordinated Phosphate. Control of pH comes from hydrolysis of trisodium phosphate in water Na3PO4 + H2O -> Na2HPO4 + NaOH. Molar ratio of sodium : phosphate is 3 : 1 in water Feedwater contamination usually dictates caustic-consuming chemicals, such as disodium and trisodium phosphate Does not ensure absence of caustic
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disadvantages of trisodium phosphate dosing in high pressure boiler
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EP0640747A1 - Boiler system pH/phosphate program control . High pressure and/or high capacity boilers generally are water-tube boilers in which water is The inert tracer overcomes problems with phosphate "hideout", which causes Thus, one mole of …
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The use of phosphate chemicals for internal boiler water treatment is more than 70 years old, and is currently used in about 65% of drum units worldwide. Coordinated pH-phosphate control was introduced in 1942 to protect boiler tubes from "caustic embrittlement" as well as the effects of condenser in-leakage of water hardness contaminants.
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Apr 12, 2018 · Test the coal fired boilers water every week to ensure the excessive alkalinity; if the alkalinity is not enough, add sodium hydroxide or trisodium phosphate. For the alkaline solution preparation, generally add 5-8kg of NaOH, or 4-6kg NaOH and 1-2kg Na 3 PO 4 to per ton of softened water.
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Jun 12, 2017 · Trisodium phosphate reacts in the boiler to produce caustic alkalinity and raise the pH. Careful monitoring and control of boiler water chemistry is required to maintain the equilibrium balance between pH and phosphate residual. Coordinated phosphate treatment is very effective for boilers operating in the 1000 to 1500 psig range.
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It is used in high pressure boilers. The phosphate reacts with calcium and magnesium salts to give soft sludges of calcium and magnesium phosphates. 3CaSO4 + 2Na3PO4 Ca3(PO4)2 + 2Na2SO4 Generally 3 types of phosphates are employed. Trisodium phosphate Na3PO4 (too alkaline) : used for too acidic water. Disodium hydrogen phosphate Na2HPO4 (weakly
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most often active in the high pressure boilers and HP HRSG evaporators operating 4above about 10.3 MPa water treatment. Use either trisodium phosphate plus up to 1 mg ·L–1 sodium hydroxide (NaOH) or trisodium phosphate alone always ensuring that the sodium-to-phosphate molar ratios are greater than 3.
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Apr 29, 2020 · Na 2 CO 3 can break down to form NaOH in higher rated boilers hence initial dose with Na 2 SO 4 Medium pressure tank blrs (<17.5 bar) Na 2 CO 3 (3) + sodium phosphate( 4 ) + sludge conditioners( 1 )
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High pressure boilers using demineralized water are most vulnerable to caustic corrosion. Hydrolysis of trisodium phosphate is a pH Coordinated and congruent phosphates boiler water treatment has been used for more than forty years. They are very effective scale inhibitors for low and high comparison of trisodium phosphate and naoh
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Jan 01, 2015 · Moreover, in modern high pressure boilers no solid is used as conditioning chemical to avoid any residual salts in boiler water. The most widely used oxygen scavenger as a part of volatile treatment is hydrazine which does not leave any residue (N 2 H 4 + O 2 → N 2 + 2H 2 O) in feedwater. Scavenging dissolved oxygen in feedwater is affected
Get priceTo minimize the iron deposition in high-pressure (1000-1750 psig) boilers, specific polymers have been designed to disperse the iron and keep it in the bulk water. As with phosphate precipitation and chelant control programs, the use of these polymers with coordinated phosphate/pH treatment improves deposit control.
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In high pressure boilers, Na 2 CO 3 decomposes to give sodium hydroxide and carbon dioxide, Na 2 CO 3 + H 2 O → 2NaOH + CO 2. and this makes the boiler water basic ["caustic"]. The NaOH containing water flows into the minute hair-cracks, always present in the inner side of boiler, by capillary action.
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Jun 28, 2018 · Control Parameters of Alkaline Degreasing with Soda Ash Chemical Concentration Sodium carbonate 0.5 to 1.0% by weight Sodium metasilicate 0.5 to 1.0% by weight Trisodium phosphate 0.5 to 1.0% by
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32. What is the role of phosphates in the internal treatment of water (or) Name an internal method used for high pressure boiler? (May 2005, Dec 2011) Phosphate salts are used as internal boiler compounds in high pressure boilers. Phosphates precipitate the soluble Ca and Mg salts as their insoluble phosphates.
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Sep 15, 2015 · Phosphate/Polymer Treatment Boiler Control Parameters • Phosphate residual as PO4 depending on hardness in the feedwater • usually associated with boiler pressure • and environmental legislation • M alkalinity of 700 ppm as CaCO3 (25 % of TDS) • Polymer : min 360 ppm as SP8100 • Still the most used method for treating low pressure
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Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate. Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate.
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Phosphate conditioning: Reagent added is sodium phosphate. In high pressure boilers scale formation can be avoided by adding sodium phosphate. It reacts with hardness of water forms non adherent, easily removable soft sludge of Ca / Mg phosphates. 3CaCl 2 +2Na 3 PO 4 Ca 3 (PO 4) 2 ↓+ 6NaCl Sludge
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Coordinated phosphate treatment (CPT) or captive alkalinity program was first introduced by Purcell and Whirl [27] fulfilled in high pressure boilers operating at the range of 1000-2000 PSI.
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Answer (1 of 2): Why is the trisodium phosphate added to boiler feed water? Because it reacts with dissolved scaling impurities such as Mg 2+ ans Ca 2+ to form non-scaling precipitates of calcium and magnesium phosphates. This is removed from the boiler feed water when it is regularly blown down
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NaOH + Na2HPO4 Æ Na3PO4 + H2O As shown above, feedwater caustic will react with disodium phosphate in the boiler water forming trisodium phosphate. In a similar fashion feedwater acidic species will react with trisodium phosphate to form disodium phosphate as follows: HCl + Na3PO4 Æ Na2HPO4 + NaCl
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EP0640747B1 EP94113074A EP94113074A EP0640747B1 EP 0640747 B1 EP0640747 B1 EP 0640747B1 EP 94113074 A EP94113074 A EP 94113074A EP 94113074 A EP94113074 A EP 94113074A EP 0640747 B1 EP0640747 B1 EP 0640747B1 Authority EP European Patent Office Prior art keywords tracer phosphate boiler blowdown feed Prior art date Kefid Legal …
Get priceJun 26, 2017 · From these figures we can determine the equivalent weight of any phosphate or phosphate mixture from which the P 2 0 5 content is known. Divide the equivalent weight of P 2 O 5 (23.7) by the percentage of P 2 O 5 in the product. B. Phosphate Calculation. Phosphate reacts with feedwater hardness and OH alkalinity to produce hydroxyapatite, an
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